Campo DC | Valor | Idioma |
dc.contributor.author | Cunha, Silvio do Desterro | - |
dc.contributor.author | Oliveira, Caio C. | - |
dc.creator | Cunha, Silvio do Desterro | - |
dc.creator | Oliveira, Caio C. | - |
dc.date.accessioned | 2014-02-19T13:05:10Z | - |
dc.date.available | 2014-02-19T13:05:10Z | - |
dc.date.issued | 2011 | - |
dc.identifier.issn | 0100-4042 | - |
dc.identifier.uri | http://repositorio.ufba.br/ri/handle/ri/14634 | - |
dc.description | p. 1425-1438 | pt_BR |
dc.description.abstract | This review describes the use of two biomass-derivate butenolides as intermediates in organic synthesis, mucobromic acid and its reduced derivative 3,4-dibromofuran-2(5H)-one. The ambiphilic and ambident character of such butenolides make them versatile starting materials in the synthesis of natural and/or bioactive compounds. Thus, the reactions of mucobromic acid with C-nucleophiles and heteronucleophiles are described, as well as the nucleophilic addition to carbonyl reactions of 3,4-dibromofuran-2(5H)-one. Besides, both compounds are active in diverse metal cross-coupling reactions, manly with palladium in Suzuki and Sonogashira reactions. | pt_BR |
dc.language.iso | pt_BR | pt_BR |
dc.rights | Acesso Aberto | pt_BR |
dc.source | http://dx.doi.org/10.1590/S0100-40422011000800023 | pt_BR |
dc.subject | Mucobromic acid | pt_BR |
dc.subject | 3,4-dibromofuran-2(5H)-one | pt_BR |
dc.subject | Butenolides | pt_BR |
dc.title | Aplicações sintéticas do ácido mucobrômico e da 3,4-dibromofuran-2(5H)-ona | pt_BR |
dc.title.alternative | Química Nova | pt_BR |
dc.type | Artigo de Periódico | pt_BR |
dc.identifier.number | v. 34, n. 8 | pt_BR |
Aparece nas coleções: | Artigo Publicado em Periódico (Química)
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