| Campo DC | Valor | Idioma |
|---|
| dc.contributor.author | Vidal, Robson da Silva | - |
| dc.contributor.author | Doro, Fabio Gorzoni | - |
| dc.contributor.author | Ferreira, Kleber Queiroz | - |
| dc.contributor.author | Rocha, Zênis Novais da | - |
| dc.contributor.author | Castellano, Eduardo Ernesto | - |
| dc.contributor.author | Nikolaou, Sofia | - |
| dc.contributor.author | Tfouni, Elia | - |
| dc.creator | Vidal, Robson da Silva | - |
| dc.creator | Doro, Fabio Gorzoni | - |
| dc.creator | Ferreira, Kleber Queiroz | - |
| dc.creator | Rocha, Zênis Novais da | - |
| dc.creator | Castellano, Eduardo Ernesto | - |
| dc.creator | Nikolaou, Sofia | - |
| dc.creator | Tfouni, Elia | - |
| dc.date.accessioned | 2014-11-03T12:03:01Z | - |
| dc.date.issued | 2012 | - |
| dc.identifier.uri | http://repositorio.ufba.br/ri/handle/ri/16494 | - |
| dc.description | Texto completo: acesso restrito. p. 93–96 | pt_BR |
| dc.description.abstract | The cis to trans isomerizations during the syntheses of trans-[Ru(NO)(OH)(cyclam)](PF6)2, from cis-[RuCl2(cyclam)]Cl, and [Ru(NO)Cl(cyclam)] (PF6)2, from cis-[RuCl2(dmso)4], are reported. The novel trans-[Ru(NO)(OH)(cyclam)](PF6)2 complex was characterized by X-ray crystallography and vibrational infrared and nuclear magnetic resonance spectroscopies. The Ru–N–O bond angle (176.75º) and ν(NO) (1835 cm− 1) suggest a nitrosonium character for this hydroxo complex. The crystal and molecular structure of trans-[Ru(NO)Cl(cyclam)](ClO4)2·2 H2O is also reported. Results presented here support the cis–trans isomerization observed for the first time with ruthenium cyclam complexes. | pt_BR |
| dc.language.iso | en | pt_BR |
| dc.rights | Acesso Aberto | pt_BR |
| dc.source | http://dx.doi.org/ 10.1016/j.inoche.2011.09.046 | pt_BR |
| dc.subject | Ruthenium | pt_BR |
| dc.subject | Cyclam | pt_BR |
| dc.subject | Nitrosyl | pt_BR |
| dc.subject | Nitric oxide | pt_BR |
| dc.subject | Cis–trans isomerization | pt_BR |
| dc.subject | Nitrite | pt_BR |
| dc.title | Cis–trans isomerization in the syntheses of ruthenium cyclam complexes with nitric oxide | pt_BR |
| dc.title.alternative | Inorganic Chemistry Communications | pt_BR |
| dc.type | Artigo de Periódico | pt_BR |
| dc.identifier.number | v. 15 | pt_BR |
| dc.embargo.liftdate | 10000-01-01 | - |
| Aparece nas coleções: | Artigo Publicado em Periódico (Química)
|
